Taking high-current power from a late-model vehicle really isn't a very good idea. It isn't just whether you can make it "work". Recently-designed vehicles have elaborate energy management systems that were not designed for such loads. That is why Sprinters, for example, have upfitter guidelines that forbid taking more than 40A from the chassis electrical system. In practice, this never really mattered much on the NCV-3 with the 6-cylinder engine. But, the I4 engines had a much more elaborate energy management system that (among other things) had a shunt mounted on one of the battery terminals. Which side of that shunt should one steal the power? This obviously matters, but as far as I know, nobody knows the correct answer--there probably is none.
I have no detailed knowledge of other makes, or even of the new Sprinters, but I doubt that the systems have gotten any simpler. A second alternator totally avoids this can of worms. I, for one, will never consider hacking into these systems. No certified upfitter will do so.