I was first thinking this was a 6.0L, but it's an older chassis with the 350 engine. The 6.0L engine has a freeze plug on the end of the head, but 350's don't (at least the late 70's and earlier vintage). Also, all the bolt holes on the end of a 350 head (again, late 70's and earlier) are blind holes, so nothing goes into the water jacket on the end. 2001 vintage?? I have no working experience with 350's this new.
On a 350, the lower row of head bolts and (I believe) the two end bolts on both ends of the head holding it down to the block underneath the valve cover goes into the water jacket. If any head bolts were leaking, it may only be a matter of time before it corrodes enough and starts to get into the cylinders, and then it may be a much larger job to fix with potentially catastrophic results.
Also, on the late 70's and older stuff, there's a couple fittings on the intake that go into the water jacket (for things like heater hoses etc), and then the thermostat housing is on the front and top of the intake. These are also leak point possibilities.
As booster said, this could be a leaking head gasket, head bolt, the end of the intake manifold bolt/gasket or leaking from a fitting above this area and wicking down to where you can see it. Unfortunately, you're probably going to have to take off the serpentine belt system at a minimum to get a good look at that area to see where the water may be starting from.